Monday, July 5, 2021

Hydrogen Bibliography

2 comments:

Anonymous said...

A hydrogen economy is another bad idea touted by the dum dums at Scientific American and other Big Science outlets. Hydrogen has to be compressed. Hydrogen gas is a small molecule that leaks easily. Hydrogen must be made by cracking water molecules using nuke power.

CP said...

As I started being more and more bothered by the hype on hydrogen, soon I saw what the real problem was. Back in the 1980s, in Berkeley, we already knew that the critical feature of fuel cells of the kind that can work near room temperature (called PEM, polymer electrode membrane cells) is the need for a catalyst at the electrodes. Without a catalyst, the cell just doesn't work at room temperature and the only catalyst that can make the cell work is platinum.

Of course, platinum is expensive, but that's not the main problem, as I discovered when I started getting involved in studies on mineral depletion. If you were to replace the current vehicles with fuel cells, there would be no way to produce enough platinum from mines (for details, you can see this 2014 article of mine). Indeed, the two years I had spent at the Lawrence Berkeley Lab were dedicated to finding ways to use less platinum, or something else in place of platinum. It wasn't just me working on it, it was a whole research group, one of the several engaged on the subject.

There are several tricks you can play to reduce the platinum loading in fuel cells. You can use small particles and exploit their large surface/volume ratio. But small particles are highly active, they move, react with each other to form larger particles, and, eventually, your electrode no longer works. Of course, there are tricks to stabilize small particles: one of the things I worked on was platinum alloys. At times, some of these alloys seemed to work little miracles. But the problem was that the miracle worked only for a while, then something happened, the alloy "de-alloyed" and the catalyst didn't work anymore. Not the right kind of behavior for something that you expect to work on a commercial vehicle for at least ten years.

Today, the problem has not been solved. I looked at a recent review on this subject and I saw that people are still struggling with the same problems I had when I worked as a young postdoc in Berkeley: reducing the platinum loading on the electrode by using alloys.

https://cassandralegacy.blogspot.com/2020/12/the-hydrogen-hoax-confessions-of-former.html